Crystal structure of Cs[(UO2)2(C2O4)2(OH)] · H2O

被引：0
|
作者：
L. B. Serezhkina
E. V. Peresypkina
A. V. Virovets
I. V. Medrish
D. V. Pushkin
机构：
[1] Samara State University,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of Inorganic Chemistry | 2009年 / 54卷
关键词：
Cesium; Coordination Polyhedron; Symmetry Code; Cesium Atom; Uranium Atom;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Single crystals of Cs[(UO2)2(C2O4)2(OH)] · H2O were synthesized and structurally studied using X-ray diffraction. The compound crystallizes in monoclinic space group P21/m, Z = 2, with the unit cell parameters a = 5.5032(4) Å, b = 13.5577(8) Å, c = 9.5859(8) Å, β = 97.012(3)°, V = 709.86(9) Å3, R = 0.0444. The main building units of crystals are [(UO2)2(C2O4)2(OH)]− layers of the A2K202M2 (A = UO22+, K02 = C2O42−, and M2 = OH−) crystal-chemical family. Uranium-containing layers are linked into a three-dimensional framework via electrostatic interactions with outer-sphere cations and hydrogen bonds with water molecules.
引用
收藏
页码：1577 / 1580
页数：3
相关论文
共 50 条
  • [41] Synthesis and crystal structure of Rb2[(UO2)2(C2O4)2(SeO4)] · 1.33H2O
    I. V. Medrish
    E. V. Peresypkina
    A. V. Virovets
    L. B. Serezhkina
    Russian Journal of Coordination Chemistry, 2008, 34 : 629 - 634
  • [42] Synthesis and structures of Cs4[(UO2)2(C2O4)(SO4)2(NCS)2] • 4H2O and (NH4)4[(UO2)2(C2O4)(SO4)2(ncs)2] • 6H2O
    Medrish, I. V.
    Virovets, A. V.
    Peresypkina, E. V.
    Serezhkina, L. B.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (07) : 1034 - 1039
  • [43] CRYSTAL-STRUCTURE OF CS2MN2(C2O4)3.3H2O . 3 H2O
    SIEMS, H
    LOHN, J
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1972, 393 (02): : 97 - &
  • [44] Synthesis and crystal structure of Ba2[(UO2)(C2O4)2(NCS)]NCS·7H2O
    Zh. V. Akhmerkina
    E. V. Peresypkina
    A. V. Virovets
    L. B. Serezhkina
    Russian Journal of Coordination Chemistry, 2006, 32 : 297 - 303
  • [45] Synthesis and crystal structure of Ba2[(UO2)(C2O4)2(NCS)]NCS•7H2O
    Akhmerkina, ZV
    Peresypkina, EV
    Virovets, AV
    Serezhkina, LB
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2006, 32 (04) : 297 - 303
  • [46] Synthesis and X-ray diffraction study of Li(H3O)[UO2(C2O4)2(H2O)] • H2O
    Shilova, M. Yu.
    Vologzhanina, A. V.
    Serezhkina, L. B.
    Serezhkin, V. N.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2009, 54 (11) : 1763 - 1767
  • [47] X-ray Diffraction Study of the Crystals of (NH4)6[(UO2)2(C2O4)(SeO4)4] • 2H2O and Refinement of the Crystal Structure of [UO2C2O4 • H2O] • 2H2O
    Mikhailov, Yu. N.
    Gorbunova, Yu. E.
    Shishkina, O. V.
    Serezhkina, L. B.
    Serezhkin, V. N.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 1999, 44 (09) : 1370 - 1375
  • [48] Synthesis and X-ray diffraction study of Li(H3O)[UO2(C2O4)2(H2O)] · H2O
    M. Yu. Shilova
    A. V. Vologzhanina
    L. B. Serezhkina
    V. N. Serezhkin
    Russian Journal of Inorganic Chemistry, 2009, 54 : 1763 - 1767
  • [49] Synthesis and x-ray diffraction of (CN3H6)2[UO2(C2O4)2(H2O)] • H2O
    Artem'eva, MY
    Mikhailov, YN
    Gorbunova, YE
    Serezhkina, LB
    Serezhkin, VN
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2005, 50 (08) : 1173 - 1176
  • [50] Synthesis and crystal structure of [Nd(H2O)2]2(C2O4)3
    Trombe, JC
    Jaud, J
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2003, 33 (01) : 19 - 26
12345