Crystal structure of Cs[(UO2)2(C2O4)2(OH)] · H2O

被引：0
|
作者：
L. B. Serezhkina
E. V. Peresypkina
A. V. Virovets
I. V. Medrish
D. V. Pushkin
机构：
[1] Samara State University,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of Inorganic Chemistry | 2009年 / 54卷
关键词：
Cesium; Coordination Polyhedron; Symmetry Code; Cesium Atom; Uranium Atom;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Single crystals of Cs[(UO2)2(C2O4)2(OH)] · H2O were synthesized and structurally studied using X-ray diffraction. The compound crystallizes in monoclinic space group P21/m, Z = 2, with the unit cell parameters a = 5.5032(4) Å, b = 13.5577(8) Å, c = 9.5859(8) Å, β = 97.012(3)°, V = 709.86(9) Å3, R = 0.0444. The main building units of crystals are [(UO2)2(C2O4)2(OH)]− layers of the A2K202M2 (A = UO22+, K02 = C2O42−, and M2 = OH−) crystal-chemical family. Uranium-containing layers are linked into a three-dimensional framework via electrostatic interactions with outer-sphere cations and hydrogen bonds with water molecules.
引用
收藏
页码：1577 / 1580
页数：3
相关论文
共 50 条
  • [1] Synthesis and crystal structure of Cs2[(UO2)2(C2O4)3] and Cs2[UO2(C3H2O4)2] · H2O
    L. B. Serezhkina
    E. V. Peresypkina
    Ya. A. Medvedkov
    A. V. Virovets
    V. N. Serezhkin
    Russian Journal of Inorganic Chemistry, 2013, 58 : 1465 - 1469
  • [2] Synthesis and structures of Cs4[(UO2)2(C2O4)(SO4)2(NCS)2] • 4H2O and (NH4)4[(UO2)2(C2O4)(SO4)2(ncs)2] • 6H2O
    Medrish, I. V.
    Virovets, A. V.
    Peresypkina, E. V.
    Serezhkina, L. B.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (07) : 1034 - 1039
  • [3] Synthesis and structures of Cs4[(UO2)2(C2O4)(SO4)2(NCS)2] · 4H2O and (NH4)4[(UO2)2(C2O4)(SO4)2(NCS)2] · 6H2O
    I. V. Medrish
    A. V. Virovets
    E. V. Peresypkina
    L. B. Serezhkina
    Russian Journal of Inorganic Chemistry, 2008, 53 : 1034 - 1039
  • [4] Crystal structure of Ba3[UO2(C2O4)2(NCS)]2 · 9H2O
    Zh. V. Akhmerkina
    E. V. Peresypkina
    A. V. Virovets
    L. B. Serezhkina
    Russian Journal of Inorganic Chemistry, 2008, 53 : 1396 - 1400
  • [5] Crystal structure of Ba3[UO2(C2O4)2(NCS)]2 • 9H2O
    Akhmerkina, Zh. V.
    Peresypkina, E. V.
    Virovets, A. V.
    Serezhkina, L. B.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (09) : 1396 - 1400
  • [6] Synthesis and structure of M[UO2(C2O4)(NCS)] · 0.5H2O (M = Rb or Cs)
    I. V. Medrish
    E. V. Peresypkina
    A. V. Virovets
    L. B. Serezhkina
    Russian Journal of Inorganic Chemistry, 2008, 53 : 1040 - 1045
  • [7] Synthesis and crystal structure of Rb2[(UO2)2(C2O4)2(SeO4)] • 1.33H2O
    Medrish, I. V.
    Peresypkina, E. V.
    Virovets, A. V.
    Serezhkina, L. B.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2008, 34 (08) : 629 - 634
  • [8] Synthesis and crystal structure of Rb2[(UO2)2(C2O4)2(SeO4)] · 1.33H2O
    I. V. Medrish
    E. V. Peresypkina
    A. V. Virovets
    L. B. Serezhkina
    Russian Journal of Coordination Chemistry, 2008, 34 : 629 - 634
  • [9] Synthesis and X-ray diffraction study of Li(H3O)[UO2(C2O4)2(H2O)] · H2O
    M. Yu. Shilova
    A. V. Vologzhanina
    L. B. Serezhkina
    V. N. Serezhkin
    Russian Journal of Inorganic Chemistry, 2009, 54 : 1763 - 1767
  • [10] Synthesis and structure of (NH4)2[(UO2)2(C2O4)(CH3COO)4] · 2H2O
    L. B. Serezhkina
    A. V. Vologzhanina
    N. A. Neklyudova
    V. N. Serezhkin
    M. Yu. Antipin
    Russian Journal of Inorganic Chemistry, 2008, 53 : 1193 - 1196
12345