Hydrosilylation of Vinylsiloxanes with Hydrosiloxanes in the Presence of Thermo- and Photoactivated Platinum(II) Phosphine Complexes

被引：0
|
作者：
D. A. de Vekki
N. K. Skvortsov
机构：
[1] St. Peterburg State Institute of Technology,
来源：
Russian Journal of General Chemistry | 2004年 / 74卷
关键词：
Platinum; Phosphine; Catalytic Property; Platinum Complex; Neutral Ligand;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Catalytic properties of thermo- and photoactivated platinum complexes [Pt(R2R'X)2Cl2] (X = P, R = Me, R' = Ph; X = P, As, Sb, R = R' = Ph or Bu) in hydrosilylation of vinylsiloxanes with hydrosiloxanes were studied. The neutral ligands were ranked in terms of their effect on the activity of the catalysts. A mechanism of hydrosilylation was proposed.
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页码：197 / 206
页数：9
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