Doubly excited triplet states of highly stripped ions

被引:0
|
作者
Das A.K. [1 ]
Mukherjee P.K. [1 ]
Thakkar A.J. [2 ]
机构
[1] Department of Spectroscopy, Indian Assoc. the Cultiv. of Sci., Jadavpur
[2] Department of Chemistry, University of New Brunswick, Fredericton
关键词
PACS. 31.50.+w Excited states[:AND:] 32.80.Dz Autoionization;
D O I
10.1007/PL00021628
中图分类号
学科分类号
摘要
Transition energies, Coulomb repulsions and effective quantum numbers have been calculated for the doubly excited Nsnp: 3P0 (for N = 2, n = N, . . . , 5); Nsnd: 3De (for N = 2, n = N + 1, . . . , 5) and Npnd: 3F0 (for N = 2, n = N + 1, . . . , 5) states for the highly stripped ions Na9+, Mg10+, Al11+, Si12+, P13+ and S14+. Time-dependent perturbation theory has been applied to calculate such transitions properties. A time-dependent harmonic perturbation causes simultaneous excitation of both the electrons with a change of spin state. The doubly excited energy levels and the analytic representation of their wave functions are obtained by identifying the poles of an appropriately constructed linearized variational functional with respect to driving frequency. Most of the results are new. The transition energies and effective quantum numbers of 2s2p: 3P0 states of all the ions agree well with the only available experimental data.
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页码:451 / 456
页数:5
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