Copoly(arylene phthalides) in the thermal polymerization of styrene

被引:0
|
作者
A. R. Ayupova
T. A. Yangirov
B. M. Abdullin
R. Kh. Yumagulova
A. A. Fatykhov
V. A. Kraikin
机构
[1] Ufa Federa1 Research Center of the Russian Academy of Sciences,Ufa Institute of Chemistry
来源
Russian Chemical Bulletin | 2021年 / 70卷
关键词
styrene; thermoinitiated polymerization; polymer initiators; copolyarylene phthalides; micelles;
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学科分类号
摘要
The thermal polymerization of styrene in the presence of polymer initiators, copoly(arylene phthalides) of the diphenyl oxide series with different ratios of two adjacent (“head-to-head”) and single (“head-to-tail”) phthalide groups, was studied. Depending on the composition of copoly(arylene phthalides), either copolymers enriched in styrene units, or copolymers with prevailing arylphthalide groups are formed. Diphilic macromolecules of the copolymers form micelles in solutions, the size of which is determined by the ratio of styrene and phthalide units.
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页码:1804 / 1815
页数:11
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