Single-ion approach to the interpretation of the x-ray photoelectron spectra of the valence bands of monoxides of 3d elements

被引：0
作者：
L. D. Finkel’shtein
E. I. Zabolotskii
V. R. Galakhov
É. Z. Kurmaev
S. Ulenbrok
S. Bartkovski
M. Noimann
机构：
[1] Ural Branch of the Russian Academy of Sciences,Institute of Metal Physics
来源：
Physics of the Solid State | 1997年 / 39卷
关键词：
Spectroscopy; State Physics; Fine Structure; Valence Band; Statistical Weight;
D O I：
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中图分类号：
学科分类号：
摘要：
The single-ion approach taking account of only the intra-atomic Coulomb interaction in free dn ions and in dn ions in an Oh crystal field is used to analyze the fine structure of the x-ray photoelectron spectra of the valence bands of monoxides of 3d elements. The x-ray photoelectron spectra were studied as a collection of dn−1 and dnL multiplets representing the unscreened and screened parts, respectively, of the final state. The unscreened part of the final state can be described by the distribution of the line strengths of the photoelectronic transition dn → dn−1 and the screened part can be described as a partially relaxed distribution of the statistical weights of the dn ions.
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页码：948 / 954
页数：6
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