meso-spacer influence on properties of zinc(II) complexes with 2,3′- and 3,3′-bis(dipyrrolylmethenes)

被引：0
|
作者：
L. A. Antina
G. B. Guseva
A. I. V’yugin
E. V. Antina
M. B. Berezin
机构：
[1] Russian Academy of Sciences,Krerstov Institute of Solution Chemistry
来源：
Russian Journal of General Chemistry | 2013年 / 83卷
关键词：
General Chemistry; Fluorescence Quantum Yield; Pyrrol Ring; Thermal Destruction; Zinc Acetate Dihydrate;
D O I：
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中图分类号：
学科分类号：
摘要：
The study and comparative analysis of spectral-luminescent characteristics (absorption and fluorescence spectra), of quantum yield, and fluorescence life time in solutions, of lability in proton-donor media, solid phase thermal stability in air oxygen and argon was carried out for binuclear zinc(II) helicates with decamethyl-substituted 2,3′- and 3,3′-bis(dipyrrolylmethenes). The influence of molecular structure features of the ligands on the physicochemical properties of helicates was discussed.
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页码：1143 / 1150
页数：7
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