Thermodynamics of nanostructured materials

被引:0
作者
V. I. Vigdorovich
L. E. Tsygankova
机构
[1] Tambov State Technical University,Chemistry of Nanomaterials Department
[2] Derzhavin Tambov State University,undefined
来源
Protection of Metals and Physical Chemistry of Surfaces | 2012年 / 48卷
关键词
NANOSTRUCTURED Material; Effective Size; Sodium Atom; Excess Gibbs Free Energy; Effective Particle Size;
D O I
暂无
中图分类号
学科分类号
摘要
Published data on the influence of the effective nanoparticle size and the atomicity of clusters on the physicochemical properties of substances are considered. An interpretation is suggested for the analytical relations of the first and second laws of thermodynamics considered with conversion of the substance and the dependence of the chemical potential of reagents on the effective nanoparticle size taken into account.
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页码:501 / 507
页数:6
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