On the finite-field transition dipole moment calculations by effective Hamiltonian methods

被引：0
|
作者：
A. Zaitsevskii
A.P. Pychtchev
机构：
[1] Laboratory of Molecular Structure and Quantum Mechanics,
[2] Physical Chemistry,undefined
[3] Chemical Department,undefined
[4] M. Lomonosov Moscow State University,undefined
[5] 119899 Moscow,undefined
[6] Russia,undefined
来源：
The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics | 1998年 / 4卷
关键词：
PACS. 31.25.-v Electron correlation calculations for atoms and molecules - 31.50.+w Excited states - 33.70.Ca Oscillator and band strengths, lifetimes, transition moments, and Franck-Condon factors;
D O I：
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学科分类号：
摘要：
A simple finite-field scheme of calculations on electronic transition dipole moments in molecules by effective Hamiltonian methods is presented and discussed. The reliability of underlying approximations is analyzed by means of the quasidegenerate perturbation theory and corroborated by the results of pilot numerical applications.
引用
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页码：303 / 308
页数：5
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