Association and Solvation of Silver Nitrate and Perchlorate in Aqueous Ethanol

The molar conductivities of silver nitrate and perchlorate solutions in aqueous ethanol (XEtOH = 0.5–0.9 and XEtOH = 0.9, respectively) were measured. Using the conductometry data, the values of dissociation constants and limiting conductivities (λ0) of these electrolytes were calculated. The results were discussed by employing a solvation-thermodynamic approach. The hydrodynamic radii of Ag+, NO3-\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ {\text{NO}}_{3}^{ - } $$\end{document} and ClO4-\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ {\text{ClO}}_{4}^{ - } $$\end{document} ions were estimated.