Nature of intramolecular O→Si bond in N-(trifluorosilylmethy)succinimide and N-(trifluorosilylmethy)phthalimide

被引：0
|
作者：
M. S. Nechaev
T. N. Aksamentova
M. G. Voronkov
N. N. Chipanina
O. M. Trofimova
Yu. I. Bolgova
V. K. Turchaninov
机构：
[1] Moscow State University,Favorskii Irkutsk Institute of Chemistry, Siberian Branch
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of General Chemistry | 2009年 / 79卷
关键词：
General Chemistry; Silicon Atom; Bond Critical Point; Succinimide; Phthalimide;
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学科分类号：
摘要：
By AIM analysis with application of PBE/TZ2P(SBK-JC) method the O→Si bond in isolated molecules of N-(trifluorosilylmethyl)succinimide (I) and N-(trifluorosilylmethyl)phthalimide (II) is shown to be of donor-acceptor type. In crystalline state of compound I it also is a weak donor-acceptor bond, while in II the interaction between the oxygen and silicon atoms is of electrostatic nature.
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页码：1086 / 1089
页数：3
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