A simple algorithm for the calculation of an approximate electrophoretic mobility of a spherical colloidal particle based on the modified Poisson-Boltzmann equation

被引：0
作者：
Hiroyuki Ohshima
机构：
[1] Tokyo University of Science,Faculty of Pharmaceutical Sciences
来源：
Colloid and Polymer Science | 2017年 / 295卷
关键词：
Electrophoretic mobility; Modified Poisson-Boltzmann equation; Effects of ionic size; Spherical colloidal particle;
D O I：
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中图分类号：
学科分类号：
摘要：
A simple algorithm is presented for the calculation of an approximate electrophoretic mobility of a spherical colloidal particle in an electrolyte solution. The obtained expressions are based on an approximate form of the modified Poisson-Boltzmann equation taking into account the ion size effects through Carnahan-Starling activity coefficients of electrolyte ions (J Chem Phys 51:635,31). Agreement with the exact numerical results by López-García et al. (J Colloid Interface Sci 458:273,27) is good for most practical cases.
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页码：543 / 548
页数：5
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