Partial oxidation of ethane in a fuel cell-like electrochemical reactor in the gas phase under mild conditions

被引:0
作者
A. O. Kuzmin
E. R. Savinova
V. N. Parmon
机构
[1] Boreskov Institute of Catalysis,
来源
Reaction Kinetics and Catalysis Letters | 1999年 / 66卷
关键词
Ethane; light paraffins; partial oxidation; gas-diffusion electrode;
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摘要
Partial oxidation of ethane with dioxygen in a gas-phase, fuel cell-like electrochemical reactor under mild conditions is reported. Ethane is shown to be selectively oxidized to ethanol and acetaldehyde on the carbon gas-diffusion cathode in the presence of transition metal ions (Fe2+, Cu2+). The reaction proceeds at ambient pressure and temperature in the range from 318 to 353 K.
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页码:147 / 153
页数:6
相关论文
共 27 条
[1]  
Otsuka K.(1992)undefined J. Electrochem. Soc. 139 2381-2381
[2]  
Kunieda M.(1993)undefined J. Chem. Soc. Faraday Trans. 89 1791-1791
[3]  
Yamagata H.(1994)undefined J. Chem. Soc. Faraday Trans. 90 451-451
[4]  
Yamanaka I.(1990)undefined J. Electrochem. Soc. 137 2007-2007
[5]  
Otsuka K.(1991)undefined Langmuir 7 13-13
[6]  
Yamanaka I.(1991)undefined J. Electrochem. Soc. 138 3176-3176
[7]  
Otsuka K.(1990)undefined J. Electrochem. Soc. 137 2076-2076
[8]  
Cook R.L.(1992)undefined Catal. Lett. 12 353-353
[9]  
Sammels A.F.(1994)undefined Catal. Lett. 27 355-355
[10]  
Frese K.W.(undefined)undefined undefined undefined undefined-undefined