The nature of internal conversion and intersystem crossing in exciplexes

被引：0
作者：
M. G. Kuzmin
I. V. Soboleva
E. V. Dolotova
D. N. Dogadkin
机构：
[1] Moscow State University,
来源：
High Energy Chemistry | 2005年 / 39卷
关键词：
Experimental Data; Physical Chemistry; Electron Transfer; Internal Conversion; Quantum Transition;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Experimental data obtained by the authors themselves and other published data on the dependence of the rate constants of internal conversion and intersystem crossing in exciplexes (back electron transfer) on the value of energy gap were critically revisited. The conclusion that these processes occur according to the mechanism of radiationless diabatic quantum transitions, rather than the preceding thermally activated solvent and reactant reorganizations was substantiated.
引用
收藏
页码：86 / 96
页数：10
相关论文
共 129 条
[21]  
Calcacerra L.T.(2004)undefined Khim. Vys. Energ. 38 434-undefined
[22]  
Closs G.L.(2004)undefined Khim. Vys. Energ. 38 440-undefined
[23]  
Miller J.R.(1974)undefined Proc. Natl. Acad. Sci. U.S.A. 71 3640-undefined
[24]  
Beitz J.V.(1970)undefined Molecular Physics 18 145-undefined
[25]  
Huddleston R.K.(1975)undefined J. Chem. Phys. 63 4358-undefined
[26]  
Wasielewski M.R.(1981)undefined J. Am. Chem. Soc. 103 741-undefined
[27]  
Niemczyk N.P.(1984)undefined J. Chem. Phys. 81 4494-undefined
[28]  
Svec W.A.(1969)undefined Adv. Photochem. 7 149-undefined
[29]  
Pewitt E.B.(1950)undefined Proc. R. Soc. London, A 204 406-undefined
[30]  
Irvine M.P.(1994)undefined Prog. Reaction Kinetics 19 317-undefined
12345678910