The nature of internal conversion and intersystem crossing in exciplexes

被引：0
作者：
M. G. Kuzmin
I. V. Soboleva
E. V. Dolotova
D. N. Dogadkin
机构：
[1] Moscow State University,
来源：
High Energy Chemistry | 2005年 / 39卷
关键词：
Experimental Data; Physical Chemistry; Electron Transfer; Internal Conversion; Quantum Transition;
D O I：
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学科分类号：
摘要：
Experimental data obtained by the authors themselves and other published data on the dependence of the rate constants of internal conversion and intersystem crossing in exciplexes (back electron transfer) on the value of energy gap were critically revisited. The conclusion that these processes occur according to the mechanism of radiationless diabatic quantum transitions, rather than the preceding thermally activated solvent and reactant reorganizations was substantiated.
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页码：86 / 96
页数：10
相关论文
共 129 条
[1]  
Kuzmin M.G.(2003)undefined Photochem. Photobiol. Sci. 2 967-undefined
[2]  
Soboleva I.V.(1999)undefined J. Am. Chem. Soc. 121 1688-undefined
[3]  
Dolotova E.V.(1997)undefined J. Photochem. Photobiol., A 111s. 41-undefined
[4]  
Dogadkin D.N.(1997)undefined J. Photochem. Photobiol., A 118 157-undefined
[5]  
Hubig S.M.(1996)undefined J. Photochem. Photobiol., A 102 51-undefined
[6]  
Kochi J. K.(1993)undefined Pure Appl. Chem. 65 1653-undefined
[7]  
Jacques P.(1956)undefined J. Chem. Phys. 24 966-undefined
[8]  
Allonas X.(1997)undefined Pure Appl. Chem. 69 13-undefined
[9]  
Von Raumer M.(1993)undefined J. Phys. Chem. 97 5911-undefined
[10]  
Suppan P.(1984)undefined J. Am. Chem. Soc. 106 3047-undefined
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