Green Synthesized Carbon Quantum Dots from Polianthes tuberose L. Petals for Copper (II) and Iron (II) Detection

被引：0
作者：
Bipin Rooj
Ankita Dutta
Sahidul Islam
Ujjwal Mandal
机构：
[1] The University of Burdwan,Department of Chemistry
[2] Triveni Devi Bhalotia College,Department of Chemistry
来源：
Journal of Fluorescence | 2018年 / 28卷
关键词：
Carbon quantum dot; Tuberose petals; Green synthesis; Fluorescence quenching; Metal ion sensing;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In this work carbon quantum dots (CQDs) are synthesized via a simple, low cost and as well as green way using tuberose (Polianthes tuberose L.) petals as the carbon source for the first time. We have not done any surface modification to the prepared CQDs although we directly employed this as fluorescent probe for the sensitive and selective detection of Fe2+ and Cu2+ ions. Both these ions drastically quench the emission intensity of the CQDs; in case of Cu2+ ions quenched CQDs EDTA results in regaining the fluorescence property but for Fe2+ ions quenched CQDs no such effect of EDTA is found. The limit of detection (LOD) is observed to be 200 nM in case of Cu2+ which is much lower than the safe limit provided by the WHO in drinking water. Hence the CQDs prepared in this simple and low cost method may find an important role in monitoring the water quality. The quantum yield of the CQDs prepared in our method is around 3%. Transmission electron microscope shows picture of nicely shaped CQDs with average size ~ 4 nm.
引用
收藏
页码：1261 / 1267
页数：6
相关论文
共 159 条
  • [11] Wei W(2015)Green anhydrous synthesis of hydrophilic carbon dots on large-scale and their application for broad fluorescent pH sensing Chem Lett 44 1251-1253
  • [12] Bhattacharyya K(2006)Hydrothermal Synthesis of Fluorescent Carbon Dots towards Ion Response and Silk Screen Patterns Environ Health Perspect 114 165-6744
  • [13] Mukherjee S(2010)A Toxicologic review of quantum dots: toxicity depends on physicochemical and environmental factors Angew Chem Int Ed 49 6726-259
  • [14] Bhattacharyya S(2013)Luminescent carbon Nanodots: emergent Nanolights Nano-Micro Lett 5 247-750
  • [15] Ehrat F(2012)Controllable Synthesis of Fluorescent Carbon Dots and Their Detection Application as Nanoprobes J Am Chem Soc 134 747-652
  • [16] Urban P(2014)Formation mechanism of Carbogenic nanoparticles with dual photoluminescence emission Sensors Actuators B 196 647-3137
  • [17] Teves R(2016)One-step green synthesized fluorescent carbon nanodots from bamboo leaves for copper(II) ion detection J Mater Chem C 4 3131-393
  • [18] Wyrwich R(2016)White light emission from a mixture of pomegranate extract and carbon nanoparticles obtained from the extract Mater Today 19 382-1395
  • [19] Döblinger M(2017)Carbon dots: large-scale synthesis, sensing and bioimaging J Phys Chem Lett 8 1389-381
  • [20] Feldmann J(2015)pH-elicited luminescence functionalities of carbon dots: mechanistic insights Chem Soc Rev 44 362-2822
12345678910