Study of the synergistic effect of nickel phosphate nanotubes (NiPO-NT) on intumescent flame retardant polypropylene composites

被引:0
作者
Xiang Dong
ShiBin Nie
ZeGong Liu
De-yi Wang
机构
[1] Anhui University of Science and Technology,Key Laboratory of Safe and Effective Coal Mining of Ministry of Education, School of Energy Resources and Safety
[2] IMDEA Mat Inst,undefined
来源
Journal of Thermal Analysis and Calorimetry | 2016年 / 126卷
关键词
Nickel phosphate nanotubes; Intumescent flame retardant (IFR); Synergistic effect; Polypropylene;
D O I
暂无
中图分类号
学科分类号
摘要
The nickel phosphate nanotubes (NiPO-NT) were synthesized by hydrothermal method, and its structure was characterized. Then NiPO-NT was added to intumescent flame retardants system in polypropylene (PP) matrix for the first time,and the synergistic effect of NiPO-NT with intumescent flame retardants was studied. The results show that only small content of NiPO-NT can obviously improve the flame retardant and thermal properties of intumescent flame retardant PP composite. With the addition of 0.3 % NiPO-NT, the peak heat release rate of intumescent flame retardant PP composite decreases from 374.7 to 255.5 kW m−2, and the limit oxygen index value increases from 29.9 to 33.9. Meanwhile, the maximum mass loss temperature under N2 atmosphere is increased from 408 to 483 °C.
引用
收藏
页码:1323 / 1330
页数:7
相关论文
共 111 条
[1]  
Nie SB(2008)Study on a novel and efficient flame retardant synergist-nanoporous nickel phosphates VSB-1 with intumescent flame retardants in polypropylene Polym Adv Technol 19 489-495
[2]  
Hu Y(2015)Thermal oxidative degradation kinetics of novel intumescent flame-retardant polypropylene composites J Therm Anal Calorim 120 1183-1191
[3]  
Song L(2014)Double-layered co-microencapsulated ammonium polyphosphate and mesoporous MCM–41 in intumescent flame-retardant natural rubber composites J Therm Anal Calorim 115 1173-1181
[4]  
He SQ(2015)Study of the synergistic effect of nanoporous nickel phosphates on novel intumescent flame retardant polypropylene composites J Spectrosc 110 165-174
[5]  
Yang DD(2014)One-pot synthesis of a novel s-triazine-based hyperbranched charring foaming agent and its enhancement on flame retardancy and water resistance of polypropylene Polym Degrad Stabil 105 12-20
[6]  
Nie SB(2014)Synergistic effect between a novel triazine charring agent and ammonium polyphosphate on flame retardancy and thermal behavior of polypropylene Polym Degrad Stabil 22 1824-1831
[7]  
Zhou C(2011)Preparation of gel-silica/ammonium polyphosphate core-shell flame retardant and properties of polyurethane composites Polym Adv Technol 117 693-699
[8]  
Peng C(2014)Synergistic effect of organophilic Fe-montmorillonite on flammability in polypropylene/intumescent flame retardant system J Therm Anal Calorim 117 1065-1071
[9]  
Liu L(2014)Synergistic effects and mechanism of ZnCl J Therm Anal Calorim 112 359-368
[10]  
Zhang C(2015) on intumescent flame-retardant polypropylene J Therm Anal Calorim 52 6303-6310