Amino acid hydration in aqueous magnesium and sodium sulfate solutions

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作者
V. P. Korolev
A. L. Serebryakova
机构
[1] Russian Academy of Sciences,G. A. Krestov Institute of Solution Chemistry
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关键词
partial volume; amino acids; water-salt systems; group contributions; hydration numbers;
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摘要
We study the partial volumes of amino acids in aqueous magnesium and sodium sulfate solutions, which have a different effect on the structure of water, and calculate the structural parameters of hydrated complexes of NH3+ and COO− groups: hydration numbers and water volumes inside and outside the hydration shell. The hydration numbers are given as a sum of the contributions of the interactions in the ternary (water-salt-amino acid) and binary (water-salt) systems.
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页码:72 / 76
页数:4
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