Self-doping Effects on the Superconducting Properties of Cu0.5Tl0.25M0.25Ba2Ca2Cu3O10−δ (M = Bi, Hg, Nb, Pd, Li, Na, K)

The effect of self-doping and substitution of elements of higher and lower electronegativity, such as Bi, Hg, Nb, Pd, Li, Na, K, on the superconducting properties of Cu0.5Tl0.5−xMxBa2Ca2Cu3O10−δ with x=0.25 is investigated. These experiments demonstrated that the elements of lower electronegativity such as Li, Na, and K can easily liberate their outer most s-electron that could be supplied to the conducting CuO2 planes of Cu0.5Tl0.5−xMxBa2Ca2Cu3O10−δ superconductor, and as a result, we get enhanced superconducting properties. However, highly electro-negative elements hinder the transfer of carriers from charge reservoir layer to the conducting CuO2 planes and promote inferior superconducting properties. In the present studies, we have investigated the effect of post-annealing in nitrogen and oxygen atmospheres for optimizing the carriers in conducting CuO2 planes of Cu0.5Tl0.5−xMxBa2Ca2Cu3O10−δ (M=Bi,Hg,Nb,Pd,Li,Na,K) superconductor. These studies are important since the density of carriers in the conducting CuO2 planes determines the Fermi-vector kF and Fermi velocity vF of the carriers, which ultimately brings about the final superconducting state of the system.