Some Structural and Thermodynamic Aspects of Solvation of Single Ions. 1. Thermodynamic Characteristics of Solvation of Single-Charged Ions in Water and Methanol and Their Structural Terms

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作者
V. I. Parfenyuk
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[1] Institute of Solution Chemistry,Russian Academy of Sciences
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Methanol; Physical Chemistry; Hydration; Inorganic Chemistry; Structural Change;
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摘要
The Gibbs energies of hydration of monoatomic single-charged ions (298.15 K) were calculated based on the previously developed concept about the real thermodynamic properties of single ions. The structural terms of the thermodynamic functions of ion solvation in water and methanol, defining structural changes in the solvent in the near solvation region, were evaluated.
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页码:946 / 950
页数:4
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