Nanostructure-based plasmon-enhanced Raman spectroscopy for surface analysis of materials

被引：0
作者：
Song-Yuan Ding
Jun Yi
Jian-Feng Li
Bin Ren
De-Yin Wu
Rajapandiyan Panneerselvam
Zhong-Qun Tian
机构：
[1] State Key Laboratory for Physical Chemistry of Solid Surfaces,
[2] College of Chemistry and Chemical Engineering,undefined
[3] iChEM,undefined
[4] Xiamen University,undefined
[5] MOE Key Laboratory of Spectrochemical Analysis and Instrumentation,undefined
[6] Xiamen University,undefined
来源：
Nature Reviews Materials | / 1卷
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摘要：
Since 2000, there has been an explosion of activity in the field of plasmon-enhanced Raman spectroscopy (PERS), including surface-enhanced Raman spectroscopy (SERS), tip-enhanced Raman spectroscopy (TERS) and shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS). In this Review, we explore the mechanism of PERS and discuss PERS hotspots — nanoscale regions with a strongly enhanced local electromagnetic field — that allow trace-molecule detection, biomolecule analysis and surface characterization of various materials. In particular, we discuss a new generation of hotspots that are generated from hybrid structures combining PERS-active nanostructures and probe materials, which feature a strong local electromagnetic field on the surface of the probe material. Enhancement of surface Raman signals up to five orders of magnitude can be obtained from materials that are weakly SERS active or SERS inactive. We provide a detailed overview of future research directions in the field of PERS, focusing on new PERS-active nanomaterials and nanostructures and the broad application prospect for materials science and technology.
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