Extraction of chlororuthenium(III) complexes from hydrochloric acid solutions by petroleum sulfoxides

被引：0

作者：

N. G. Afzaletdinova

L. M. Ryamova

Yu. I. Murinov

R. V. Kunakova

机构：

[1] Ufa Scientific Center,Institute of Organic Chemistry

[2] Ufa State Academy for Economics and Service,undefined

来源：

Russian Journal of Inorganic Chemistry | 2007年 / 52卷

关键词：

Ruthenium; Distribution Ratio; Hydrochloric Acid Solution; Decanol; Extraction Complex;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The extraction of ruthenium(II) by petroleum sulfoxides (PSOs) from hydrochloric acid solutions has been studied. The extraction of ruthenium(III) by PSOs is implemented by the coordination mechanism with the incorporation of the sulfoxide oxygen atom of the extractant into the inner coordination sphere of the ruthenium(III) ion. The composition of the extraction compound is suggested using electronic, 1H NMR, and IR spectroscopy, the slope method, and elemental analysis.

引用

页码：806 / 811

页数：5

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