Suzuki-Miyaura coupling on heterogeneous palladium catalysts

被引:0
|
作者
Attila Papp
Diána Tóth
Árpád Molnár
机构
[1] Department of Organic Chemistry,
[2] University of Szeged,undefined
[3] ,undefined
[4] Department of Organic Chemistry,undefined
[5] University of Szeged,undefined
[6] ,undefined
[7] Department of Organic Chemistry,undefined
[8] University of Szeged,undefined
[9] ,undefined
来源
Reaction Kinetics and Catalysis Letters | 2006年 / 87卷
关键词
catalysis; palladium; Suzuki coupling; boron; base effect; biaryls;
D O I
暂无
中图分类号
学科分类号
摘要
Five supported heterogeneous Pd catalysts have been prepared, characterized and found to be active and selective in the Suzuki-Miyaura coupling of boronic acids, and aromatic iodo and bromo compounds to form the corresponding biaryls in high selectivities. Reaction conditions, namely, the solvent, base (triethylamine, Na2CO3, Cs2CO3) and tetrabutylammonium chloride as an additive are shown to have profound effects on catalyst performance.</o:p>
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页码:335 / 342
页数:7
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