Study of lithium complexes with benzo-15-crown-5 ether by X-ray diffraction and IR spectroscopy

被引：0
作者：
L. I. Demina
L. G. Kuz’mina
S. V. Demin
N. A. Shokurova
V. I. Zhilov
A. Yu. Tsivadze
机构：
[1] Russian Academy of Sciences,Frumkin Institute of Physical Chemistry and Electrochemistry
[2] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
来源：
Russian Journal of Inorganic Chemistry | 2017年 / 62卷
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摘要：
The complex formation of lithium with benzo-15-crown-5 (B15C5) was investigated. The complexes LiB15C5H2OX, where X = Cl− (1), I− (2), (3), (5), and LiBF4B15C5 (4) were synthesized and studied by IR spectroscopy. Complexes 1–4 were examined by X-ray diffraction. According to IR spectroscopy data, the crown ether conformation changes upon dissolution. The interaction of the extracted complex with the solvent was identified.
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页码：1536 / 1543
页数：7
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