MPEG-b-poly(amino urethane) amphiphilic block copolymers and their pH-Dependent micellization behavior

被引：0
作者：
Kasala Dayananda
Chaoliang He
Ying Qian Hu
Min Sang Kim
Doo Sung Lee
机构：
[1] Sungkyunkwan University,Polymer Technology Institute
[2] Sungkyunkwan University,Department of Polymer Science and Engineering
来源：
Macromolecular Research | 2009年 / 17卷
关键词：
Pyrene; Block Copolymer; Dynamic Light Scattering; Triblock Copolymer; Polymeric Micelle;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The MPEG-PAU block coplymers were successfully synthesized and their chemical structures were well characterized by1H,13C NMR and FT-IR spectroscopies. The aqueous solution properties of the copolymers were evaluated by acid-base titration, fluorescence spectroscopy and dynamic light scattering. The block copolymers exhibited a pHdependent micellization-demicellization transition in aqueous solution. The fluorescence spectroscopy and DLS measurements indicate that the micellization-demicellization transition occurs at pH 6.0–6.6. The amphiphilic block copolymers are expected to find applications in biomedical field.
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页码：58 / 61
页数：3
相关论文
共 68 条
[11]  
Bae Y. H.(2005)undefined Macromol. Res. 13 467-467
[12]  
Lee E. S.(2002)undefined Macromolecules 35 8540-8540
[13]  
Na K.(2007)undefined Macromol. Res. 15 385-385
[14]  
Bae Y. H.(2006)undefined Macro. Rapid Commun. 27 447-447
[15]  
Tannock I. F.(2007)undefined Macromol. Res. 15 437-437
[16]  
Rotin D.(2006)undefined Macromol. Res. 14 117-117
[17]  
Kang S. I.(2005)undefined Macromol. Res. 13 147-147
[18]  
Bae Y. H.(undefined)undefined undefined undefined undefined-undefined
[19]  
Shim W. S.(undefined)undefined undefined undefined undefined-undefined
[20]  
Lee J. S.(undefined)undefined undefined undefined undefined-undefined
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