Transesterification of palm cooking oil using barium-containing titanates and their sodium doped derivatives

被引：11

作者：

Chew K.Y. ^{[1
]}

Tan W.L. ^{[1
]}

Abu Bakar N.H.H. ^{[1
]}

Abu Bakar M. ^{[1
]}

机构：

[1] School of Chemical Sciences, Universiti Sains Malaysia, Penang

来源：

International Journal of Energy and Environmental Engineering | 2017年 / 8卷 / 01期

关键词：

Ba[!sub]2[!/sub]NiTi[!sub]5[!/sub]O[!sub]13[!/sub; BaTiO[!sub]3[!/sub; Catalyst; Sodium-doped; Transesterification;

D O I：

10.1007/s40095-016-0222-4

中图分类号：

学科分类号：

摘要：

BaTiO3, Ba2NiTi5O13 and their Na-doped analogues were successfully synthesized via sol–gel and calcination methods. The surface properties of the prepared catalysts were characterized by scanning electron microscopy and nitrogen adsorption–desorption analysis while the basicity was determined by benzoic acid titration. The catalytic activity of the Ba-based catalysts was verified in transesterification of palm cooking oil with methanol. The optimization study was conducted by varying the oil:methanol ratio, catalyst loading, reaction temperature and duration. The highest methyl ester (ME) yield was ~95% for 5 wt/v% Na-Ba2NiTi5O13 at a methanol to oil ratio of 12:1 at 150 °C for 2 h. © 2016, The Author(s).

引用

页码：47 / 53

页数：6

共 36 条

[1]

Sajjada B., Abdul Rahman A.A., Arandiyah H., A comprehensive review on properties of edible and non-edible vegetable oil-based biodiesel: composition, specifications and prediction models, Renew Sust Energy Rev, 63, pp. 62-92, (2016)

[2]

Demirbas A., Biodiesel: a realistic fuel alternative for diesel engines, (2007)

[3]

Leung D.Y.C., Wu X., Leung M.K.H., A review on biodiesel production using catalyzed transesterification, Appl Energy, 87, pp. 1083-1095, (2010)

[4]

Avhad M.R., Marchetti J.M., Innovation in solid heterogeneous catalysis for the generation of economically viable and ecofriendly biodiesel: a review, Catal Rev Sci Eng, 58, pp. 157-208, (2016)

[5]

Chorkendoff I., Niemantsverdriet J.W., Concepts of modern catalysis and kinetic, (2003)

[6]

Mar W., Samsook E., Methanolysis of soybean oil over KCl/CaO solid base catalyst for biodiesel production, Sci Asia, 38, pp. 90-94, (2012)

[7]

Olutoye M.A., Wong S.W., Chin L.H., Amani H., Asif M., Hameed B.H., Synthesis of fatty acid methyl esters via the transesterification of waste cooking oil by methanol with a barium-modified montmorillonite K10 catalyst, Renew Energy, 86, pp. 392-398, (2016)

[8]

Mukenga M., Muzenda E., Jalama K., Mijiboom R., Biodiesel production from soybean oil over TiO<sub>2</sub> supported nano-ZnO, Int J Chem Nucl Mater Metall Eng, 6, pp. 348-352, (2012)

[9]

Lee H.V., Taufiq-Yap Y.H., Hussein M.Z., Yunus R., Transesterification of jatropha oil with methanol over Mg–Zn mixed metal oxide catalysts, Energy, 49, pp. 12-18, (2013)

[10]

Fan M., Liu Y., Zhang P., Jiang P., Blocky shapes Ca-Mg mixed oxides as a water-resistant catalyst for effective synthesis of biodiesel by transesterification, Fuel Process Technol, 149, pp. 163-168, (2016)

← 1 2 3 4 →