Synthesis and structures of silicon-, germanium-, and tin-containing tungsten carbyne complexes (ButO)3W≡C—EPh3 and [(ButO)3W≡C]2EPh2 (E = Si, Ge, Sn)

被引：0
|
作者：
A. V. Safronova
L. N. Bochkarev
N. E. Stolyarova
I. K. Grigor"eva
I. P. Malysheva
G. V. Basova
G. K. Fukin
Yu. A. Kurskii
S. Ya. Khorshev
G. A. Abakumov
机构：
[1] Russian Academy of Sciences,G. A. Razuvaev Institute of Organometallic Chemistry
来源：
Russian Chemical Bulletin | 2003年 / 52卷
关键词：
carbyne complexes; synthesis; X-ray diffraction analysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
New tungsten carbyne complexes (ButO)3W≡C—SiPh3, [(ButO)3W≡C]2SiPh2, [(ButO)3W≡C]2GePh2, and [(ButO)3W≡C]2SnPh2 were prepared by the reactions of (But)6W2 with Ph3SiC≡C—Pr or Ph2E(C≡C—Pr)2 (E = Si, Ge, Sn) in individual crystalline form in 48—80% yields. The structures of both the (ButO)3W≡C—GePh3 and (ButO)3W≡C—SnPh3 compounds synthesized earlier and the new complexes were established by X-ray diffraction analysis.
引用
收藏
页码：2140 / 2145
页数：5
相关论文
共 50 条
  • [1] Synthesis and structures of silicon-, germanium-, and tin-containing tungsten carbyne complexes (ButO)3W≡EPh3 and [(ButO)3W≡C]EPh2 (E = Si, Ge, Sn)
    Safronova, AV
    Bochkarev, LN
    Stolyarova, NE
    Grigor'eva, IK
    Malysheva, IP
    Basova, GV
    Fukin, GK
    Kurskii, VA
    Khorshev, SY
    Abakumov, GA
    RUSSIAN CHEMICAL BULLETIN, 2003, 52 (10) : 2140 - 2145
  • [2] New tungsten carbyne complexes containing the triphenylgermyl and triphenylstannyl groups at the carbyne carbon atom (ButO)3W≡C—EPh3 (E = Ge, Sn)
    L. N. Bochkarev
    A. V. Safronova
    V. I. Shcherbakov
    N. E. Stolyarova
    G. V. Basova
    S. Ya. Khorshev
    Yu. A. Kurskii
    G. A. Abakumov
    Russian Chemical Bulletin, 2002, 51 : 552 - 553
  • [3] New tungsten carbyne complexes containing the triphenylgermyl and triphenylstannyl groups at the carbyne carbon atom (ButO)3W≡C-EPh3 (E = Ge, Sn)
    Bochkarev, LN
    Safronova, AV
    Shcherbakov, VI
    Stolyarova, NE
    Basova, GV
    Khorshev, SY
    Kurskii, YA
    Abakumov, GA
    RUSSIAN CHEMICAL BULLETIN, 2002, 51 (03) : 552 - 553
  • [4] Synthesis of trinuclear silicon-, germanium-, and tin-containing tungsten carbene complexes [(ButO)2(Cl)2W = CH]2EPh2 (E = Si, Ge, or Sn).: Crystal structure of [(ButO)2(Cl)2W=CH]2SiPh2 complex
    Safronova, AV
    Bochkarev, LN
    Stolyarova, NE
    Grigorieva, IK
    Malysheva, IP
    Basova, GV
    Fukin, GK
    Kurskii, YA
    Abakumov, GA
    RUSSIAN CHEMICAL BULLETIN, 2005, 54 (11) : 2502 - 2505
  • [5] Synthesis of trinuclear silicon-, germanium-, and tin-containing tungsten carbene complexes [(ButO)2(Cl)2W=CH]2EPh2 (E = Si, Ge, or Sn). Crystal structure of [(ButO)2(Cl)2W=CH]2SiPh2 complex
    A. V. Safronova
    L. N. Bochkarev
    N. E. Stolyarova
    I. K. Grigorieva
    I. P. Malysheva
    G. V. Basova
    G. K. Fukin
    Yu. A. Kurskii
    G. A. Abakumov
    Russian Chemical Bulletin, 2005, 54 : 2502 - 2505
  • [6] Synthesis and structures of silicon-, germanium- and tin-containing tungsten imido alkyl complexes (ArN)2W(CH2EMe3)2 (E = Si, Ge, Sn)
    Bochkarev, LN
    Scherbakov, VI
    Malysheva, IP
    Basova, GV
    Stolyarova, NE
    Grigorieva, IK
    Bochkarev, AL
    Fukin, GK
    Kurskii, YA
    Abakumov, GA
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (05) : 983 - 986
  • [7] Synthesis and structures of silicon-, germanium-, and tin-containing imido-alkyl molybdenum complexes (ArN)2MO(CH2EMe3)2 (E = Si, Ge, Sn)
    Bochkarev, LN
    Nikitinskii, AV
    Skatova, AA
    Begantsova, YE
    Shcherbakov, VI
    Malysheva, IP
    Basova, GV
    Fukin, GK
    Kurskii, VA
    Khorshev, SY
    Barinova, YP
    Abakumov, GA
    RUSSIAN CHEMICAL BULLETIN, 2005, 54 (03) : 606 - 609
  • [8] Synthesis and structures of silicon-, germanium-, and tin-containing imido-alkyl molybdenum complexes (ArN)2Mo(CH2EMe3)2 (E = Si, Ge, Sn)
    L. N. Bochkarev
    A. V. Nikitinskii
    A. A. Skatova
    Yu. E. Begantsova
    V. I. Shcherbakov
    I. P. Malysheva
    G. V. Basova
    G. K. Fukin
    Yu. A. Kurskii
    S. Ya. Khorshev
    Yu. P. Barinova
    G. A. Abakumov
    Russian Chemical Bulletin, 2005, 54 : 606 - 609
  • [9] Reactions of silicon-, germanium- and tin-containing carbene complexes of tungsten Ph3E-CW(OBut)3(E = Si, Ge, Sn) with hydrogen chloride:: crystal structures of carbene complexes Ph3E-CH=WCl2(OBut)2 (E = Si, Ge)
    Safronova, AV
    Bochkarev, LN
    Stolyarova, NE
    Grigorieva, IK
    Malysheva, IP
    Basova, GV
    Fukin, GK
    Kurskii, YA
    Khorshev, SY
    Abakumov, GA
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (07) : 1127 - 1130
  • [10] SYNTHESIS AND CHARACTERIZATION OF M2(EPH3)2(NME2)4 COMPOUNDS (E = C, SI, GE, SN, M = MO, W)
    CHISHOLM, MH
    GAMA, GJ
    PARKIN, IP
    POLYHEDRON, 1993, 12 (08) : 961 - 965
12345