Yttrium tris-propionate monohydrate: Synthesis, crystal structure, and thermal stability

被引:0
|
作者
I. A. Martynova
D. M. Tsymbarenko
N. P. Kuz’mina
机构
[1] Moscow State University,
来源
Russian Journal of Coordination Chemistry | 2014年 / 40卷
关键词
Yttrium; Propionic Acid; Yttrium Atom; Metal Acetylacetonates; Dimeric Fragment;
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学科分类号
摘要
The complex [Y(Prop)3(H2O)]∞ (I) was prepared by treating yttrium carbonate, acetate, or acetylacetonate hydrates with propionic acid and characterized by the data of elemental analysis, IR spectroscopy, X-ray diffraction, and thermal analysis in air. Complex I has a polymeric layered structure with clear-cut structure-forming dimeric groups bridged by bidentate ligands. Only van der Waals interactions occur between the adjacent polymeric layers. In air, yttrium propionate monohydrate I is completely converted to the oxide at 600°C.
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页码:565 / 570
页数:5
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