ESR study of some iminoxy free radicals generated from phosphorylated oximes and dioximes

被引：0
|
作者：
A. V. Il’yasov
A. A. Vafina
E. Breuer
G. Hägele
机构：
[1] Arbusov Institute of Organic and Physical Chemisry,Department of Pharmaceutical Chemistry
[2] Hebrew University of Jerusalem,Institute of Inorganic and Structure Chemistry
[3] Heinrich-Heine-University of Düsseldorf,undefined
来源：
Applied Magnetic Resonance | 1998年 / 14卷
关键词：
Oxime; Phosphorus Atom; Hyperfine Coupling; Hyperfine Coupling Constant; Spin Density Distribution;
D O I：
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学科分类号：
摘要：
The new type of phosphoniminoxy free radicals was generated electrochemically or by chemical oxidation of oximes. It was established the strong difference of ESR parameters for isomeric Z and E forms of the radicals. The spin distribution and its correlation with electronic and spatial characteristics of molecules as well as with intramolecular interactions are discussed.
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页码：489 / 496
页数：7
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