Thermally stable and processible norbornene copolymers

被引:0
作者
Dong-Woo Yoo
Seung-Jae Yang
Jin-Kyu Lee
Joohyeon Park
Kookheon Char
机构
[1] Seoul National University,School of Chemistry
[2] Seoul National University,School of Chemical and Biological Engineering
来源
Macromolecular Research | 2006年 / 14卷
关键词
polynorbornene copolymers; solubility; thermal stability; adhesion;
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摘要
Processible norbornene copolymers were realized by judiciously designing norbornene comonomers, which were themselves prepared by the Diels-Alder reaction of cyclopentadiene and benzoquinone followed by the isomerization and alkylation of alcohols. The norbornene copolymers containing these derivatized comonomers, prepared by [Pd(NCCH2CH3)4][SbF6]2 catalyst, exhibited excellent solubility in many organic solvents as well as good thermal stability, as evidenced by their high glass transition (Tg) and decomposition (∼350°C) temperatures. In addition, fairly strong adhesion to substrates such as glasses and silicon wafers was also achieved with these copolymers to overcome the limitations experienced by polynorbornene homopolymers and to make them attractive for many important industrial applications.
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页码:107 / 113
页数:6
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共 44 条
  • [1] Maya E. M.(2004)undefined Macromol. Rapid Commun. 25 592-592
  • [2] Lozano A. E.(1999)undefined J. Polym. Sci.; Part B: Polym. Phys. 37 3003-3003
  • [3] Campa J. G.(2001)undefined Macromol. Rapid Commun. 22 479-479
  • [4] Abajo J.(2000)undefined Macromolecules 33 4313-4313
  • [5] Grove N. R.(1993)undefined Makromol. Chem. 194 37-37
  • [6] Kohl P. A.(1992)undefined Macromolecules 25 6593-6593
  • [7] Allen S. A. B.(1991)undefined Makromol. Chem. Rapid Commun. 12 255-255
  • [8] Jayaraman S.(1992)undefined Macromolecules 25 4226-4226
  • [9] Shick R.(1999)undefined Ind. Eng. Chem. Res. 38 4675-4675
  • [10] Janiak C.(1996)undefined Macromolecules 29 2755-2755