An optical resolution of racemic organophosphorous esters by phosphotriesterase-catalyzing hydrolysis

被引：0

作者：

Shokichi Ohuchi

Hiroyuki Nakamura

Hlroto Sligiura

Mltsuaki Narita

Koji Sode

机构：

[1] Tokyo University of Agriculture and Technology,Department of Biotechnology

来源：

Applied Biochemistry and Biotechnology | 1997年 / 63-65卷

关键词：

Phosphotriesterase; stereospecific reaction; organophosphorous; insecticide; phosphotriesters; kinetic optical resolution;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

We have shown that PTE chiral recognition is limited to organophosphorous esters having the chiral center on the phosphorous atoms, which is attacked with nucleophile, not having the chiral center on the other atoms of the leaving group. Therefore, PTE can be utilized for the synthesis of their chiral organophosphorous esters.

引用

页码：659 / 665

页数：6

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