Crystal structure of copper(II) chelate with para-(tert-butyl)benzoic acid N′,N′-dimethylhydrazide

被引：0
|
作者：
V. Yu. Gusev
D. A. Muksinova
P. A. Slepukhin
A. V. Radushev
机构：
[1] Russian Academy of Sciences,Institute of Technical Chemistry, Ural Branch
[2] Russian Academy of Sciences,Postovsky Institute of Organic Synthesis, Ural Branch
来源：
Russian Journal of Coordination Chemistry | 2012年 / 38卷
关键词：
Benzoic Acid; Tert; Tert Butyl Group; Metal Ring; Donor Acceptor Bond;
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摘要：
X-Ray diffraction analysis was performed for the copper(II) chelate with para-(tert-butyl)benzoic acid N′,N′-dimethylhydrazide, Cu(p-(tert-Bu)C6H4CONHNMe2)2 (I). The reagent functions as a bidentate (O,N(2)) ligand giving a five-membered copper-containing ring. The molecule is centrosymmetric. The Cu atom and the metal rings lie in the same plane. The coordination polyhedron of copper is a slightly distorted square. The crystals are monoclinic: a = 16.2634(14) Å, b = 9.0415(8) Å, c = 9.6415(9) Å, α = 90°, β = 100.052(7)°, Z = 2, space group P21/c.
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页码：515 / 518
页数：3
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