Relationship between the internal pressure and cohesive energy density of a liquid nonelectrolyte. Consequences of application of Dack’s concept

被引：0
作者：
E. V. Ivanov
V. K. Abrosimov
机构：
[1] Russian Academy of Sciences,Institute of Solution Chemistry
来源：
Journal of Structural Chemistry | 2005年 / 46卷
关键词：
liquid medium; alkanol; internal pressure; cohesive energy density; intermolecular interactions; structure;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Dack’s concept that correlates internal pressure with cohesive energy density of a liquid system is shown to be applicable to identification of energy and structural changes in series of alkanols: MeOH, EtOH, n-PrOH, (i-PrOH), and n-BuOH, (t-BuOH). The side chain of methyl groups that appears in the molecule loosens the structural packing of the alkanol, creating additional steric hindrances for stable hydrogen bonds in alcohol media.
引用
收藏
页码：856 / 861
页数：5
相关论文
共 63 条
[1]  
Richards T. W.(1925)undefined Chem. Rev. 2 315-280
[2]  
Rodnikova M. N.(1993)undefined Zh. Fiz. Khim. 67 275-1018
[3]  
Kartsev V. N.(2002)undefined Zh. Fiz. Khim. 76 1016-1463
[4]  
Rodnikova M. N.(2003)undefined Zh. Fiz. Khim. 77 1456-98
[5]  
Bartel J.(2004)undefined Zh. Strukt. Khim. 45 94-882
[6]  
Shtykov S. N.(2004)undefined Zh. Strukt. Khim. 45 877-40
[7]  
Kartsev V. N.(1971)undefined J. Paint Technol. 43 35-2798
[8]  
Rodnikova M. N.(1973)undefined J. Phys. Chem. 77 2794-1648
[9]  
Shtykov S. N.(1975)undefined Austral. J. Chem. 28 1643-757
[10]  
Bartel J.(1989)undefined Ind. J. Pure Appl. Phys. 27 751-228
1234567