A morpholinium-functionalized poly(ether sulfone) as a novel anion exchange membrane for alkaline fuel cell

被引:0
作者
So-Jung Hahn
Mihee Won
Tae-Hyun Kim
机构
[1] Incheon National University,Organic Material Synthesis Laboratory, Department of Chemistry
来源
Polymer Bulletin | 2013年 / 70卷
关键词
Anion exchange membrane; Morpholinium-functionalized polymer; Poly(ether sulfone); Conductivity; Stability;
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摘要
A methyl morpholinium-functionalized poly(ether sulfone) (MM-PES) copolymer was prepared as a novel anion exchange membrane. The MM-PES polymer was synthesized by polycondensation between the morpholine-containing hydroquinone and bisphenol A with bis(4-fluorophenyl)sulfone, followed by methylation of the morpholine group. The membrane obtained from MM-PES showed an IEC of 0.90 meq/g with high hydroxide conductivity of 1.6 × 10−2 S/cm at r.t. and 7.9 × 10−2 S/cm at 80 °C. The methyl morpholinium-functionalized PES membrane also displayed good hydrolytic, thermal, mechanical and chemical stabilities.
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页码:3373 / 3385
页数:12
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