Triphenylbismuth Bis(2,4,6-Tribromophenoxide): Synthesis and Structure

被引：0
作者：
V. V. Sharutin
O. K. Sharutina
I. V. Egorova
I. I. Pavlushkina
M. A. Pushilin
A. V. Gerasimenko
机构：
[1] Blagoveshchensk State Pedagogical University,Institute of Chemistry, Far East Division
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of Coordination Chemistry | 2004年 / 30卷
关键词：
Hydrogen; Ether; Physical Chemistry; Hydrogen Peroxide; Bond Length;
D O I：
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中图分类号：
学科分类号：
摘要：
A reaction of triphenylbismuth with 2,4,6-tribromophenol and hydrogen peroxide (molar ratio 1 : 2 : 1) in ether affords triphenylbismuth bis(2,4,6-tribromophenoxide). The complex obtained was structurally characterized by X-ray diffraction analysis. The coordination polyhedron of the Bi atom is a trigonal bipyramid with axial aroxy groups. The Bi–C and Bi–O bond lengths are 2.202(4), 2.203(4), 2.212(4) and 2.241(3), 2.245(3) Å, respectively. The intramolecular Bi···Br(1,4) contacts are 3.629(1) and 4.077(1) Å, respectively.
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页码：23 / 26
页数：3
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