Prototropic Rearrangement of 2-Propynyl(methyl)amino, 2-Propynyloxy, and 2-Propynylsulfanyl Derivatives of Hetarenes under Conditions of Phase-Transfer Catalysis: Mechanism and Limitations

被引：0

作者：

K. Rubina

M. Fleisher

E. Abele

Yu. Popelis

E. Lukevits

机构：

[1] Latvian Institute of Organic Synthesis,

来源：

Russian Journal of Organic Chemistry | 2003年 / 39卷

关键词：

Methyl; Sulfide; Phenol; Organic Chemistry; Catalysis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

2-Propynyl derivatives of N-methylaniline, phenol, benzenethiol, 2-pyridinethiol, 2-pyrimidinethiol, and 1,3-benzoxazole-2-thiol were synthesized. Under conditions of phase-transfer catalysis, phenyl 2-propynyl sulfide is converted into allenyl phenyl sulfide and phenyl 1-propynyl sulfide. The rearrangement mechanism was studied by the AM1 quantum-chemical method.

引用

页码：963 / 967

页数：4

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