Pulse radiolysis study of I− oxidation with radical anions Cl2⋅− in an aqueous solution

被引：0
|
作者：
B. G. Ershov
E. Janata
A. V. Gordeeva
机构：
[1] Russian Academy of Sciences,Institute of Physical Chemistry
[2] Hahn-Meitner Institute,undefined
来源：
Russian Chemical Bulletin | 2005年 / 54卷
关键词：
pulse radiolysis; redox reactions; halides; chlorine; iodine; ions; radicals; kinetics; reaction mechanism; reaction rate constants;
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摘要：
Radiation-chemical transformations of chloride solutions in the presence of iodide additives were studied by pulse radiolysis. Radical anion Cl2⋅− oxidize I− ion, while in the secondary reactions Cl2 reacts with I− to form a mixed trihalide ion ICl2−. A reaction model that satisfactorily describes the experimental data was proposed.
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页码：1378 / 1382
页数：4
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