Catalytic oxidation of furan and hydrofuran compounds. 6. Oxidation of furan by hydrogen peroxide in the presence of vanadium compounds under the conditions of phase-transfer catalysis

被引：0

作者：

Poskonin V.V. ^{[1
]}

Badovskaya L.A. ^{[1
]}

Povarova L.V. ^{[1
]}

Ponomarenko R.I. ^{[1
]}

机构：

[1] Kuban State Technological University, Krasnodar

来源：

Chemistry of Heterocyclic Compounds | 1999年 / 35卷 / 10期

关键词：

Oxidation; Polymerization; Hydrogen Peroxide; Catalysis; Hydrocarbon;

D O I：

10.1007/BF02323370

中图分类号：

学科分类号：

摘要：

Oxidation of furan in system containing hydrogen peroxide, vanadium compound, chlorinated hydrocarbon, water, and phase-transfer catalyst was studied for the first time. In addition to the main product of this process - cis-β-formylacrylic acid - the formation of other products not previously found at oxidation of furan with hydrogen peroxide was detected. They included 2(5H)-furanone, 2,5-dihydroxy-2,5-dihydrofuran, and maleic dialdehyde. Small amounts of maleic and fumaric acids and also the product from polymerization of dihydroxydihydrofuran and dialdehyde were formed. The influence of the type of organic solvent, vanadium and phase-transfer catalysts, and the ratios of the reagents on the yield of the oxidation products were investigated. ©1999 KluwerAcademic/Plenum Publishers.

引用

页码：1143 / 1149

页数：6

共 25 条

[1] Catalytic oxidation of furan and hydrofuran compounds. 4. Oxidation of furfural by hydrogen peroxide in the presence of sodium molybdate
Grunskaya E.P.
Badovskaya L.A.
Poskonin V.V.
Yakuba Yu.F.
Chemistry of Heterocyclic Compounds, 1998, 34 (7) : 775 - 780
[2] Catalytic oxidation of furan and hydrofuran compounds. 5. Hydroxy- and ethoxydihydrofurans and ethoxyfuran - New products from the reaction of furan with hydrogen peroxide
Poskonin V.V.
Badovskaya L.A.
Povarova L.V.
Chemistry of Heterocyclic Compounds, 1998, 34 (8) : 900 - 906
[3] Catalytic oxidation reactions of furan and hydrofuran compounds 9.* characteristics and synthetic possibilities of the reaction of furan with aqueous hydrogen peroxide in the presence of compounds of niobium (ii) and (v)
V. V. Poskonin
Chemistry of Heterocyclic Compounds, 2009, 45 : 1177 - 1183
[4] CATALYTIC OXIDATION REACTIONS OF FURAN AND HYDROFURAN COMPOUNDS 9.* CHARACTERISTICS AND SYNTHETIC POSSIBILITIES OF THE REACTION OF FURAN WITH AQUEOUS HYDROGEN PEROXIDE IN THE PRESENCE OF COMPOUNDS OF NIOBIUM(II) AND (V)
Poskonin, V. V.
CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2009, 45 (10) : 1177 - 1183
[5] Catalytic oxidation of furan and hydrofuran compounds. 2. Oxidation of furfural in the hydrogen peroxide-vanadyl sulfate-sodium acetate system
Poskonin V.V.
Badovskaya L.A.
Chemistry of Heterocyclic Compounds, 1998, 34 (6) : 646 - 650
[6] Catalytic oxidation of furan and hydrofuran compounds. 8. Conversions of 2(5H)-furanone by hydrogen peroxide in media of various pH
Ponomarenko R.I.
Badovskaya L.A.
Latashko V.M.
Chemistry of Heterocyclic Compounds, 2002, 38 (09) : 1049 - 1051
[7] Catalytic oxidation of furan and hydrofuran compounds. 7. Production of 2(5h)-furanone by oxidation of furfural with hydrogen peroxide and some of its transformations in aqueous solutions
Badovskaya L.A.
Latashko V.M.
Poskonin V.V.
Grunskaya E.P.
Tyukhteneva Z.I.
Rudakova S.G.
Pestunova S.A.
Sarkisyan A.V.
Chemistry of Heterocyclic Compounds, 2002, 38 (09) : 1040 - 1048
[8] Catalytic oxidation of furan and hydrofuran compounds. 3. Synthesis of 2,5-diethoxy-2,5-dihydrofuran in the furan-hydrogen peroxide-aqueous ethanol-vanadyl sulfate system
Poskonin V.V.
Badovskaya L.A.
Povarova L.V.
Chemistry of Heterocyclic Compounds, 1998, 34 (7) : 771 - 774
[9] Kinetics of N-Phosphonomethyl Iminodiacetic Acid Catalytic Oxidation with Hydrogen Peroxide Under the Phase-Transfer Conditions
Dmitry Yu. Yushchenko
Zinaida P. Pai
Tatiana B. Khlebnikova
Catalysis Letters, 2022, 152 : 2025 - 2032
[10] Kinetics of N-Phosphonomethyl Iminodiacetic Acid Catalytic Oxidation with Hydrogen Peroxide Under the Phase-Transfer Conditions
Yushchenko, Dmitry Yu
Pai, Zinaida P.
Khlebnikova, Tatiana B.
CATALYSIS LETTERS, 2022, 152 (07) : 2025 - 2032

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