Application of the Tikhonov Regularization Method in Problems of Ellipsometic Porometry of Low-K Dielectrics

被引:2
作者
Gaidukasov R.A. [1 ,2 ]
Myakon’kikh A.V. [1 ]
Rudenko K.V. [1 ]
机构
[1] Valiev Institute of Physics and Technology, Russian Academy of Sciences, Moscow
[2] Moscow Institute of Physics and Technology (National Research University), Moscow region, Dolgoprudny
基金
俄罗斯基础研究基金会;
关键词
ellipsometric porosimetry; IC metallization systems; low permittivity nanoporous dielectrics; theory of volume filling micropores (TVFM); Tikhonov regularization method;
D O I
10.1134/S1063739722040060
中图分类号
学科分类号
摘要
Abstract: In the development of promising ULIS scaling technologies, one of the key roles is played by porous dielectrics with a low permittivity used to isolate interconnects in a metallization system. Condensation of gaseous products in the pores of such films makes it possible to solve the most important problem that prevents the integration of such films, to carry out low-damage plasma etching. However, methods for studying porosity are also based on the study of the adsorption isotherm during condensation in film pores. Therefore, the study of adsorption in pores is one of the most important practical problems arising in the creation of dielectrics with a low permittivity and the study of low-damaging methods for their structuring. The method of ellipsometric porosimetry is an easy-to-implement and accurate approach for obtaining an adsorption isotherm; however, its further analysis and determination of the pore size distribution are reduced to solving an integral equation and is an ill-posed problem. In this paper, we propose to apply Tikhonov’s regularization method to solve it. The method is verified on model data and used to study a low-k dielectric sample with an initial thickness of 202 nm and a permittivity of 2.3 based on organosilicate glass. © 2022, Pleiades Publishing, Ltd.
引用
收藏
页码:199 / 209
页数:10
相关论文
共 27 条
[1]  
Rasadujjaman M., Wang Y., Zhang L., Et al., A detailed ellipsometric porosimetry and positron annihilation spectroscopy study of porous organosilicate-glass films with various ratios of methyl terminal and ethylene bridging groups, Microporous Mesoporous Mater, 306, (2020)
[2]  
Kittel C., Introduction to Solid State Physics, (1978)
[3]  
Zahedmanesh H., Besser P.R., Wilson C.J., Croes K., Airgaps in nano-interconnects: Mechanics and impact on electromigration, J. Appl. Phys., 120, 9, (2016)
[4]  
Tompkins H.G., A User’s Guide to Ellipsometry, (1993)
[5]  
Rouessac V., Lee A., Bosc F., Durand J., Ayral A., Three characterization techniques coupled with adsorption for studying the nanoporosity of supported films and membranes, Microporous Mesoporous Mater., 111, pp. 417-428, (2008)
[6]  
Tao L., Andrew J.S., Lee B., , Small angle X-ray scattering for nanoparticle research, Chem. Rev., 116, 18, pp. 11128-11180, (2016)
[7]  
Gidley D.W., Peng H.-G., Vallery R.S., Positron annihilation as a method to characterize porous materials, Ann. Rev. Mater. Res., 36, pp. 49-79, (2006)
[8]  
Miakonkikh A.V., Smirnova E.A., Clemente I.E., Application of the spectral ellipsometry method to study the processes of atomic layer deposition, Russ. Microelectron., 50, pp. 230-238, (2021)
[9]  
Dedkova A.A., Nikiforov M.O., Mitko S.V., Kireev V.Y., Investigation of gallium nitride island films on sapphire substrates via scanning electron microscopy and spectral ellipsometry, Nanotechnol. Russ., 14, pp. 176-183, (2019)
[10]  
Orlikovskii A.A., Rudenko K.V., In situ diagnostics of plasma processes in microelectronics: The current status and immediate prospect, Part III, Russ. Microelectron., 30, pp. 275-294, (2001)