The electrosurface properties and aggregation stability of aqueous titanium-dioxide suspensions are studied in wide ranges of medium pH values and poly(methacrylic acid) concentrations. Using the 2pK model, the ionization constants of surface hydroxyl groups of titanium dioxide are found and it is established that the adsorption of poly(methacrylic acid) macromolecules substantially decreases the fraction of neutral (uncharged) hydroxyl groups and affects the ratio between the positively and negatively charged surface hydroxyl groups.
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Inst of Biocolloid Chemistry of Natl, Acad of Sciences of Ukraine, Kiev, UkraineInst of Biocolloid Chemistry of Natl, Acad of Sciences of Ukraine, Kiev, Ukraine
Moraru, V.N.
Ovcharenko, F.D.
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Inst of Biocolloid Chemistry of Natl, Acad of Sciences of Ukraine, Kiev, UkraineInst of Biocolloid Chemistry of Natl, Acad of Sciences of Ukraine, Kiev, Ukraine
Ovcharenko, F.D.
Moraru, D.V.
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Inst of Biocolloid Chemistry of Natl, Acad of Sciences of Ukraine, Kiev, UkraineInst of Biocolloid Chemistry of Natl, Acad of Sciences of Ukraine, Kiev, Ukraine
Moraru, D.V.
Yaremko, Z.M.
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Inst of Biocolloid Chemistry of Natl, Acad of Sciences of Ukraine, Kiev, UkraineInst of Biocolloid Chemistry of Natl, Acad of Sciences of Ukraine, Kiev, Ukraine