Kinetics and mechanism of diethyl sulfide oxidation by sodium peroxoborate in aqueous solutions

被引：0
作者：
V. L. Lobachev
L. M. Dyatlenko
M. Yu. Zubritskii
机构：
[1] Litvinenko Institute of Physical–Organic Chemistry and Coal Chemistry,
来源：
Kinetics and Catalysis | 2016年 / 57卷
关键词：
diethyl sulfide; sodium peroxoborate; hydrogen peroxide; oxidation; kinetics;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The kinetics of diethyl sulfide (Et2S) oxidation by aqueous sodium peroxoborate (Na2[В2(О2)2(ОН)4]) solutions in a wide acidity range (from [HClO4] = 1 mol/L to рН 12) has been studied using a kinetic distribution method. The kinetic data together with the results of 11B NMR spectroscopy demonstrate that the monoperoxoborate B(O2H)3-(OH) and diperoxoborate B(O2H)2(OH)2- anions are the active species in Et2S oxidation by sodium peroxoborate at рН 8–12. It is assumed that, at a high acidity of the medium ([HClO4] = 0.05–1.0 mol/L), peroxoboric acid (ОН)2ВООН or its protonated form (OH)2BOOH2+ are direct reactants along with Н2О2 and HOOH2+.
引用
收藏
页码：742 / 749
页数：7
相关论文
共 72 条
[1]  
Wagner G.W.(2002)undefined Ind. Eng. Chem. Res. 41 1925-undefined
[2]  
Yang Y.C.(2007)undefined Energy Fuels 21 2543-undefined
[3]  
Zhao D.(2006)undefined Chem. Rev. 106 2943-undefined
[4]  
Ren H.(2010)undefined Tetrahedron Lett. 51 6255-undefined
[5]  
Wang J.(2000)undefined J. Am. Chem. Soc. 122 1729-undefined
[6]  
Yang Y.(2004)undefined Theor. Exp. Chem. 40 161-undefined
[7]  
Zhao Y.(2002)undefined Langmuir 18 3836-undefined
[8]  
Caron S.(2005)undefined Theor. Exp. Chem. 41 302-undefined
[9]  
Dugger R.W.(1997)undefined J. Chem. Soc., Faraday Trans. 93 2537-undefined
[10]  
Ruggeri S.G.(2012)undefined Theor. Exp. Chem. 48 345-undefined
12345678