Novel molybdenum complexes with the 3,6-Di-tert-butylcatecholate ligand

被引：0
作者：
P. A. Petrov
M. Yu. Afonin
D. Yu. Naumov
S. N. Konchenko
A. V. Piskunov
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Novosibirsk State University,Razuvaev Institute of Organometallic Chemistry
[3] Russian Academy of Sciences,undefined
[4] Lobachevsky State University,undefined
来源：
Russian Journal of Coordination Chemistry | 2015年 / 41卷
关键词：
Central Metal Atom; Molybdenum Complex; Phenanthrene Quinone; Redox Active Ligand; Diselenolenes;
D O I：
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摘要：
A reaction of the cluster (Et4N)2[Mo3S7Br6] with potassium 3,6-di-tert-butyl-o-benzosemiquinolate (KSQ36) afforded the mononuclear complexes (Et4N)[Mo(Cat36)3] (I) and (Et4N)[MoO(Cat36)2(HCat36)] (II) with prismatic and octahedral environments of their central metal atoms, respectively. Complex I was also obtained by a reaction between MoCl5, sodium 3,6-di-tert-butylcatecholate (Na2Cat36), and Et4NBr. Complexes I and II were characterized by X-ray diffraction and EPR spectroscopy. The structures have been deposited with the Cambridge Structural Database (nos. 1009139 (I), 1009140 (I · 1.5THF), and 1009141 (II · Et2O)).
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页码：31 / 36
页数：5
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