Synthesis of poly(hydroxyalkanoate) from hydrolyzed linseed oil

被引：0
作者：
Elena Casini
Theo C. de Rijk
Pieter de Waard
Gerrit Eggink
机构：
[1] Agrotechnological Research Institute (ATO-DLO),
来源：
Journal of environmental polymer degradation | 1997年 / 5卷 / 3期
关键词：
Poly(hydroxyalkanoate)s (PHAs); linolenic acid; unsaturated PHA; crosslink;
D O I：
10.1007/BF02763658
中图分类号：
学科分类号：
摘要：
Pseudomonas putida was grown on a mixture of long-chain fatty acids obtained by hydrolysis of linseed oil. A poly(3-hydroxyalkanoate) containing 51.2% of unsaturated monomers was obtained. A considerable percentage (13.6%) was constituted by C14 and C16 monomers containing three double-bonds in the side chains. The polymer showed a high tendency to crosslink when it was kept in presence of air. In the crosslinked polymer no polyunsaturated monomers could be detected.
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页码：153 / 158
页数：5
相关论文
共 73 条
  • [1] Anderson A. J.(1990)undefined Microbial. Res. 54 450-472
  • [2] Dawes E. A.(1989)undefined J. Bioact. Compat. Polym. 4 296-303
  • [3] Chiellini E.(1987)undefined Makromol. Chem. Rapid Commun. 8 631-635
  • [4] Solaro R.(1994)undefined J. Bacteriol. 167 1661-1666
  • [5] Casini E.(1988)undefined Appl. Environ. Microbiol. 54 1977-1982
  • [6] Casella S.(1994)undefined Polymer 35 4595-4597
  • [7] Leporini C.(1988)undefined Polym. Commun. 29 112-115
  • [8] Picci G.(1990)undefined Int. J. Macromol. 12 158-165
  • [9] Doi Y.(1992)undefined Macromolecules 25 576-581
  • [10] Tamaki A.(1994)undefined Macromolecules 27 6358-6362
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