Coefficient of ozone mass transfer during its interaction with an aqueous solution of formic acid in a bubble column reactor

被引:0
作者
A. V. Levanov
O. Ya. Isaikina
R. B. Gasanova
V. V. Lunin
机构
[1] Moscow State University,Faculty of Chemistry
[2] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
来源
Russian Journal of Physical Chemistry A | 2017年 / 91卷
关键词
ozone; formic acid; bubble column reactor; mass transfer coefficients; rate constant;
D O I
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中图分类号
学科分类号
摘要
A way of determining the coefficient of ozone mass transfer between the gas phase and liquid aqueous phase using a test compound (formic acid) is described. The values of ozone mass transfer coefficient (in aqueous solutions of 0.1–0.55 М HClO4 and 0–1 М НСООН, and in 0.75 М H2SO4, 0.125 М KHSO4, and 0–2 М НСООН) are determined along with the rate constants of the reaction of О3 with undissociated НСООН molecules and formate ions at 21 ± 1°С.
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页码:1427 / 1431
页数:4
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