Polymers of diphenylamine-2-carboxylic acid: Synthesis, structure, and properties

被引：0
作者：
S. Zh. Ozkan
I. S. Eremeev
G. P. Karpacheva
T. N. Prudskova
E. V. Veselova
G. N. Bondarenko
G. A. Shandryuk
机构：
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
[2] OJSC Petrov Plastics Institute,undefined
来源：
Polymer Science Series B | 2013年 / 55卷
关键词：
Polyaniline; Polymer Science Series; Electronic Absorption Spectrum; Ammonium Hydroxide; Diphenylamine;
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摘要：
Polymers of diphenylamine-2-carboxylic acid are prepared by chemical oxidative polymerization in an aqueous solution of ammonium hydroxide. In accordance with the IR data, during the polymerization of diphenylamine-2-carboxylic acid in a solution of ammonium hydroxide, polymer-chain growth occurs via C-C joining into 2 and 4 positions of phenyl rings with respect to nitrogen. The distinctive feature of the polymer is the absence of quinodiimine units in its structure, even if the oxidizer is in excess. The resulting polymers are amorphous, electroactive, and thermally stable.
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页码：107 / 115
页数：8
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