Effect of Donor and Acceptor on the Mechanism of a Photochemical Reaction in Doped Single Crystals for Radical Pairs in 4-Bromo-2,6-Di-tert-Butylphenol Single Crystal Doped with 2,6-Di-tert-Butyl-p-Quinone

被引：0
作者：
D. S. Tipikin
G. G. Lazarev
A. Rieker
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
[2] Monash University,Physics Department
[3] Tübingen University,Institute of Organic Chemistry
来源：
Kinetics and Catalysis | 2001年 / 42卷
关键词：
Spectroscopy; Physical Chemistry; Electron Transfer; Photolysis; Proton Transfer;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Radical pairs produced by the photolysis of 4-bromo-2,6-di-tert-butylphenol single crystals doped with 2,6-di-tert-butyl-p-quinone are studied by EPR spectroscopy. The mechanism of radical pair generation changes from hydrogen-atom transfer to electron transfer (without proton transfer). The reasons for this change are discussed.
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页码：246 / 250
页数：4
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