Luminescence of antimony(III) halide complexes with aniline

被引：0
作者：
T. V. Sedakova
A. G. Mirochnik
V. E. Karasev
机构：
[1] Russian Academy of Sciences,Institute of Chemistry, Far East Division
来源：
Russian Journal of Physical Chemistry A | 2009年 / 83卷
关键词：
Aniline; Antimony; Luminescence Spectrum; Luminescence Excitation Spectrum; Spectral Luminescence Property;
D O I：
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中图分类号：
学科分类号：
摘要：
The antimony(III) chloride and bromide complexes with aniline, (C6H5NH3)2SbCl5·(C6H5NH3)Cl·H2O (I) and (C6H5NH3)2SbBr5 (II), were synthesized, and their spectral luminescence properties were studied. An interesting peculiarity of I and II is the possibility of selective excitation of luminescence in the π system of the (C6H5NH3)+ outer sphere anilinium cation and intrinsic luminescence of the s2 ion. The population scheme for the luminescent antimony 3P1 level in I and II is discussed using the luminescence, UV, and photoelectron spectroscopy data.
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页码：308 / 310
页数：2
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