Water structural transformation at molecular hydrophobic interfaces

被引:0
|
作者
Joel G. Davis
Kamil P. Gierszal
Ping Wang
Dor Ben-Amotz
机构
[1] Purdue University,Department of Chemistry
来源
Nature | 2012年 / 491卷
关键词
D O I
暂无
中图分类号
学科分类号
摘要
Spectroscopic measurements now reveal that at low temperatures, the water in hydrophobic hydration shells has greater tetrahedral order and fewer weak hydrogen bonds than the surrounding bulk water; this structure disappears at higher temperatures and around alcohol chains longer than 1 nanometre.
引用
收藏
页码:582 / 585
页数:3
相关论文
共 50 条
  • [31] Molecular Dynamics Study of a Nanotube-Binding Amphiphilic Helical Peptide at Different Water/Hydrophobic Interfaces
    Chiu, Chi-cheng
    Dieckmann, Gregg R.
    Nielsen, Steven O.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (51): : 16326 - 16333
  • [32] Water dynamics at the molecular interfaces
    Zhuang, Wei
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
  • [33] Unveiling the structural relaxation of microgel suspensions at hydrophilic and hydrophobic interfaces
    Liu, Wei
    Zhu, Yuwei
    Li, Yinan
    Han, Jie
    Ngai, To
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2023, 633 : 948 - 958
  • [34] A model for studying drying at hydrophobic interfaces: Structural and thermodynamic properties
    Wallqvist, A
    Gallicchio, E
    Levy, RM
    JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (28): : 6745 - 6753
  • [35] Tangible interfaces for structural molecular biology
    Gillet, A
    Sanner, M
    Stoffler, D
    Olson, A
    STRUCTURE, 2005, 13 (03) : 483 - 491
  • [36] Hydration-shell vibrational spectroscopy of molecular hydrophobic interfaces
    Ben-Amotz, Dor
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [37] Ions at Hydrophobic Aqueous Interfaces: Molecular Dynamics with Effective Polarization
    Vazdar, Mario
    Pluharova, Eva
    Mason, Phil E.
    Vacha, Robert
    Jungwirth, Pavel
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2012, 3 (15): : 2087 - 2091
  • [38] STRUCTURAL-CHANGES AT HYDROPHOBIC-HYDROPHILIC INTERFACES INDUCED BY THERMAL-CHANGES AND ISOTOPIC COMPOSITION OF THE WATER
    FUJIWARA, FY
    REEVES, LW
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1979, 57 (05): : 478 - 482
  • [39] Recent experimental advances on hydrophobic interactions at solid/water and fluid/water interfaces
    Zeng, Hongbo
    Shi, Chen
    Huang, Jun
    Li, Lin
    Liu, Guangyi
    Zhong, Hong
    BIOINTERPHASES, 2016, 11 (01) : 1 - 10
  • [40] Viscosity of Water Interfaces with Hydrophobic Nanopores: Application to Water Flow in Carbon Nanotubes
    Shaat, M.
    LANGMUIR, 2017, 33 (44) : 12814 - 12819