Structure of the complex [trans-SnF4(H2O)2· (18-crown-6)· 2H2O]

被引：0
|
作者：
M. S. Fonar’
Yu. A. Simonov
G. Bogelly
é. V. Ganin
V. O. Gelmboldt
机构：
[1] Academy of Sciences of Moldova Republic,Institute of Applied Physics
[2] Center on Structure and Diffraction Research,Physicochemical Institute of Environmental and Human Control
[3] Ministry of Education and Academy of Sciences of Ukraine,undefined
来源：
Journal of Structural Chemistry | 1999年 / 40卷
关键词：
Macrocycle; Inorganic Complex; Hydrofluoric Acid Solution; Crown Ether Complex; Crown Ether Molecule;
D O I：
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中图分类号：
学科分类号：
摘要：
The molecular and crystal structure of the title complex (I) obtained by addition of tin fluoride in a hydrofluoric acid solution to 18-crown-6 in methanol was investigated by X-ray structure analysis. The crystals are monoclinic, space group P21/n, a = 13.497(3), b = 7.806(2), c = 9.892(2) Å, β = 95.57(3)°, Z = 2 for C12H32F4O10Sn. In the polymer chain, the crown ether molecules alternate with the inorganic complexes [trans-SnF4(H2O)2] and are linked to them by O-H...O type hydrogen bonds involving the intermediate water molecules. The weak C-H...F interactions bind the chains into the layers which are parallel to the xz plane.
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页码：926 / 930
页数：4
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