Acoustic wave propagation in piezoelectric crystals of classes \documentclass[12pt]{minimal}
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\end{document}3m and 23 is studied. The crystals Tl3VS4 and Tl3TaSe4 (\documentclass[12pt]{minimal}
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\end{document}3m) of the Chalcogenide family and the crystal Bi12TiO20 (23) possess strong piezoelectric effect. Because the surface Bleustein-Gulyaev waves cannot exist in piezoelectric cubic crystals, it was concluded that new solutions for shear-horizontal surface acoustic waves (SH-SAWs) are found in the monocrystals using different electrical boundary conditions such as electrically “short” and “open” free-surfaces for the unique [101] direction of wave propagation. For the crystal Tl3TaSe4 with coefficient of electromechanical coupling (CEMC) Ke2=e2/(C×g)∼1/3, the phase velocity Vph for the new SH-SAWs can be calculated with the following formula: Vph=(Va+Vt)/2, where Vt is the speed of bulk SH-wave, Vt=Vt4(1+Ke2)1/2, Va=aKVt4, aK=2[Kte(1+Ke2)1/2−Ke2]1/2, and Vt4=(C44/ρ)1/2. It was found that the CEMC K2 evaluation for Tl3TaSe4 gave the value of K2=2(Vf−Vm)/Vf∼0.047 (∼4.7%), where Vf∼848 m/s and Vm∼828 m/s are the new-SAW velocities for the free and metallized surfaces, respectively. This high value of K2(Tl3TaSe4) is significantly greater than K2(Tl3VS4)∼3% and about five times that of K2(Bi12TiO20).